Solid state NMR study of 1,3imidazolidine-2-thione, 1,3-imidazolidine-2-selenone and some of their N-substituted derivatives
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Solid state and solution NMR studies of some new complexes of mercury selenocyanate with imidazolidine-2-thione and its derivatives
Reactions of imidazolidine-2-thione (Imt), 1,3-diazinane-2-thione (Diaz) and 1,3-diazipane-2thione (Diap) with mercury(II) selenocyanate in acetonitrile resulted in formation of 2 : 1 complexes. Both solid state and solution NMR, confirm the exocyclic sulfur atom to be the donor in all cases. Hg shielding tensors and anisotropies were calculated from the solid-state NMR spectra. Based on the so...
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متن کاملPentacarbonyl(imidazolidine-2-thione-κS)tungsten(0)
In the title complex, [W(C(3)H(6)N(2)S)(CO)(5)], the W atom displays an octa-hedral coordination with five CO mol-ecules and an imidazolidine-2-thione mol-ecule. The W(CO)(5) unit is coordinated by the cyclic thione ligand through a W-S dative bond. The W-S and C-S bond lengths are 2.599 (2) and 1.711 (9) Å, respectively. This last distance is significantly longer than that of free cyclic thio-...
متن کامل1,3-Bis(1-phenylethyl)imidazolidine-2-thione
The complete molecule of the title compound, C(19)H(22)N(2)S, is generated by crystallographic twofold symmetry with the C=S group lying on the rotation axis. The imidazolidine ring adopts a flattened twist conformation. The dihedral angle between the asymmetric part of the imidazolidine-2-thione fragment and the benzene ring is 89.49 (17)°.
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ژورنال
عنوان ژورنال: Spectroscopy
سال: 2004
ISSN: 0712-4813,1875-922X
DOI: 10.1155/2004/309130